The Potential of Sodium Silicate from Rice Husk as Corrosion Inhibitor on Mild Steel

Authors

  • Atiek Rostika Noviyanti Department of Chemistry, Faculty Mathematics and Natural Sciences, Universitas Padjadjaran Sumedang, West Java 45363, Indonesia
  • Solihudin Department of Chemistry, Faculty Mathematics and Natural Sciences, Universitas Padjadjaran Sumedang, West Java 45363, Indonesia
  • Haryono Department of Chemistry, Faculty Mathematics and Natural Sciences, Universitas Padjadjaran Sumedang, West Java 45363, Indonesia
  • Yudha P. Budiman Department of Chemistry, Faculty Mathematics and Natural Sciences, Universitas Padjadjaran Sumedang, West Java 45363, Indonesia
  • Agus Solehudin Department of Mechanical Engineering Education, Faculty of Technology and Vocational Education, Universitas Pendidikan Indonesia, West Java 40154, Indonesia
  • Muhamad Diki Permana Integrated Graduate School of Medicine, Engineering and Agricultural Sciences, University of Yamanashi, Kofu 4008511, Japan https://orcid.org/0000-0002-5871-5004

DOI:

https://doi.org/10.48048/tis.2024.7779

Keywords:

Hydrophobic, Sodium silicate, Rice husk, Contact angle, Corrosion inhibitor

Abstract

Study of sodium silicate from rice husks as coating material is reported. The extraction was conducted via precipitation method with sodium hydroxide, nitric acid and ethanol at pH 8. The resulting silica was tested as hydrophobic coating by coating it on a glass surface. Based on the value of the contact angle, silica has good hydrophobic properties. The highest hydrophobic properties were obtained from sample, which labeled as Si10A:Si5B with an average contact angle of 105.3 °. Investigation of the potential application of sodium silicate as an inhibitor of corrosion has been conducted by coating it on steel surfaces. The effect of the concentration of sodium silicate was conducted at 0, 10, 20 and 30 ppm and found that the morphology of steel coated with 20 ppm has the lowest corrosion rate with 81 % inhibition efficiency.

HIGHLIGHTS

  • The amorphous silica was successfully synthesized from rice husk using the precipitation method
  • The silica from rice husk shows hydrophobic properties with a contact angle of 105.3 °
  • Sodium silicate from rice husk has the ability as a corrosion inhibitor and has an inhibition efficiency of 81 % for 20 ppm

GRAPHICAL ABSTRACT

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References

K Jeevajothi, RT Subasri and KRCS Raju. Transparent, non-fluorinated, hydrophobic silica coatings with improved mechanical properties. Ceram. Int. 2013; 39, 2111-6.

W Pramualkijja and N Jiratumnukul. Physical properties and morphology of siloxane-polyacrylate dispersion and coating films. J. Coating. Tech. Res. 2020; 17, 1277-88.

IS Bayer. Superhydrophobic coatings from ecofriendly materials and processes: A review. Adv. Mater. Interface 2020; 7, 2000095.

F Chi, D Liu, H Wu and J Lei. Mechanically robust and self-cleaning antireflection coatings from nanoscale binding of hydrophobic silica nanoparticles. Sol. Energ. Mater. Sol. Cell. 2019; 200, 109939.

KD Kim and HT Kim. Formation of silica nanoparticles by hydrolysis of TEOS using a mixed semi-batch/batch method. J. Sol Gel Sci. Tech. 2002; 25, 183-9.

H Kaur, S Chaudhary, H Kaur, M Chaudhary and KC Jena. Hydrolysis and condensation of tetraethyl orthosilicate at the air-aqueous interface: Implications for silica nanoparticle formation. ACS Appl. Nano Mater. 2022; 5, 411-22.

E Monfort, A Mezquita, E Vaquer, I Celades, V Sanfelix and A Escrig. Ceramic manufacturing processes: Energy, environmental, and occupational health issues. Compr. Mater. Process. 2014; 8, 71-102.

M Yazdimamaghani, T Pourvala, E Motamedi, B Fathi, D Vashaee and L Tayebi. Synthesis and characterization of encapsulated nanosilica particles with an acrylic copolymer by in situ emulsion polymerization using thermoresponsive nonionic surfactant. Materials 2013; 6, 3727-41.

IA Sharaky, FA Megahed, MH Seleem and AM Badawy. The influence of silica fume, nano silica and mixing method on the strength and durability of concrete. SN Appl. Sci. 2019; 1, 575.

B Singh. Rice husk ash. Woodhead Publishing, Cambridge, 2018, p. 417-60.

N Bandumula. Rice production in Asia: Key to global food security. Proc. Natl. Acad. Sci. India Biol. Sci. 2018; 88, 1323-8.

HB Dizaji, T Zeng, I Hartmann, D Enke, T Schliermann, V Lenz and M Bidabadi. Generation of high quality biogenic silica by combustion of rice husk and rice straw combined with pre- and post-treatment strategies-A review. Appl. Sci. 2019; 9, 1083.

M Noushad, IA Rahman, A Husein, D Mohamad and AR Ismail. A simple method of obtaining spherical nanosilica from rice husk. Int. J. Adv. Sci. Eng. Inform. Tech. 2012; 2, 28-30.

R Rajan, Y Zakaria, S Shamsuddin and NFN Hassan. Robust synthesis of mono-dispersed spherical silica nanoparticle from rice husk for high-definition latent fingermark development. Arabian J. Chem. 2020; 13, 8119-32.

LT Zhuravlev. The surface chemistry of amorphous silica. Zhuravlev model. Colloid. Surface. Physicochem. Eng. Aspect. 2000; 173, 1-38.

J Schaller, A Cramer, A Carminati and M Zarebanadkouki. Biogenic amorphous silica as main driver for plant available water in soils. Sci. Rep. 2020; 10, 2424.

Y Jin, A Li, SG Hazelton, S Liang, CL John, PD Selid, DT Pierce and JX Zhao. Amorphous silica nanohybrids: Synthesis, properties and applications. Coord. Chem. Rev. 2009; 253, 2998-3014.

JG Croissant, KS Butler, JI Zink and CJ Brinker. Synthetic amorphous silica nanoparticles: Toxicity, biomedical and environmental implications. Nat. Rev. Mater. 2020; 5, 886-909.

M Ide, M El-Roz, ED Canck, A Vicente, T Planckaert, T Bogaerts, IV Driessche, F Lynen, VV Speybroeck, F Thybault-Starzyk and PVD Voort. Quantification of silanol sites for the most common mesoporous ordered silicas and organosilicas: Total versus accessible silanols. Phys. Chem. Chem. Phys. 2013; 15, 642-50.

M Rimoldi and A Mezzetti. Site isolated complexes of late transition metals grafted on silica: Challenges and chances for synthesis and catalysis. Catal. Sci. Tech. 2014; 4, 2724-40.

V Thangarasu and R Anand. Comparative evaluation of corrosion behavior of Aegle Marmelos Correa diesel, biodiesel, and their blends on aluminum and mild steel metals. In: AK Azad and M Rasul (Eds.). Advanced biofuels applications, technologies and environmental sustainability. Woodhead Publishing, Cambridge, 2019, p. 443-71.

GN Marsh and C Chew. Well man clinic in general practice. Br. Med. J. 1984; 288, 200-1.

N Zulfareen, K Kannan, T Venugopal and S Gnanavel. Synthesis, characterization and corrosion inhibition efficiency of N-(4-(Morpholinomethyl Carbamoyl Phenyl) Furan-2-Carboxamide for brass in HCl medium. Arabian J. Chem. 2016; 9, 121-35.

D Njobuenwu, EO Oboho and RH Gumus. Determination of contact angle from contact area of liquid droplet spreading on solid substrate. Leonardo Electron. J. Pract. Tech. 2007; 6, 29-38.

BP Binks, L Isa and AT Tyowua. Direct measurement of contact angles of silica particles in relation to double inversion of pickering emulsions. Langmuir 2013; 29, 4923-7.

F Deng, L Wang, Y Zhou, X Gong, X Zhao, T Hu and C Wu. Effect of nanosilica content on the corrosion inhibition of composite coatings of a filled epoxy resin grafted with a hydrophobic fluoroalkylsilane: A dual critical concentrations interpretation. RSC Adv. 2017; 7, 48876-93.

HX Nguyen, NTT Dao, HTT Nguyen and AQT Le. Nanosilica synthesis from rice husk and application for soaking seeds. IOP Conf. Ser. Earth Environ. Sci. 2019; 266, 12007.

S Mirmohamadsadeghi and K Karimi. Recovery of silica from rice straw and husk. Elsevier, Amsterdam, 2020, p. 411-33.

R Maddalena, C Hall and A Hamilton. Effect of silica particle size on the formation of calcium silicate hydrate [C-S-H] using thermal analysis. Thermochim. Acta 2019; 672, 142-9.

R Sekifuji and M Tateda. Study of the feasibility of a rice husk recycling scheme in Japan to produce silica fertilizer for rice plants. Sustain. Environ. Res. 2019; 29, 11.

SN Ishmah, MD Permana, ML Firdaus and DR Eddy. Extraction of silica from bengkulu beach sand using alkali fusion method. PENDIPA J. Sci. Educ. 2020; 4, 1-5.

LK Sakti, GAN Sheha, CPSM Radhiyah, J Nugraha, DR Eddy, MD Permana, IP Maksum and Y Deawati. Cotton fabric coating by rGO and polymethylsiloxane layer with antibacterial, hydrophobic and photothermal properties. Trends Sci. 2023; 20, 6813.

PH Chen, CC Hsu, PS Lee and CS Lin. Fabrication of semi-transparent super-hydrophobic surface based on silica hierarchical structures. J. Mech. Sci. Tech. 2011; 25, 43-7.

S Gharazi, A Ershad-Langroudi and A Rahimi. The influence of silica synthesis on the morphology of hydrophilic nanocomposite coating. Sci. Iranica 2011; 18, 785-9.

MA Shirgholami, MS Khalil-Abad, R Khajavi and ME Yazdanshenas. Fabrication of superhydrophobic polymethylsilsesquioxane nanostructures on cotton textiles by a solution-immersion process. J. Colloid Interface Sci. 2011; 359, 530-5.

U Kalapathy, A Proctor and J Shultz. A simple method for production of pure silica from rice hull ash. Bioresource Tech. 2000; 73, 257-62.

TS Hamidon, NA Ishak and MH Hussin. Enhanced corrosion inhibition of low carbon steel in aqueous sodium chloride employing sol-gel-based hybrid silanol coatings. J. Sol Gel Sci. Tech. 2021; 97, 556-71.

R Farid, K Rajan and DK Sarkar. Enhanced corrosion protection of aluminum by ultrasonically dip coated sodium silicate thin films. Surf. Coating. Tech. 2019; 374, 355-61.

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Published

2024-05-10

How to Cite

Noviyanti, A. R. ., Solihudin, S., Haryono, H., Budiman, Y. P. ., Solehudin, A. ., & Permana, M. D. . (2024). The Potential of Sodium Silicate from Rice Husk as Corrosion Inhibitor on Mild Steel. Trends in Sciences, 21(7), 7779. https://doi.org/10.48048/tis.2024.7779