Fabrication and Enhancing the Features of Chitosan/SnO2-ZnO Nanocomposites Films for Optoelectronics and Biological Applications

Authors

  • Saad Abbas Jasim Department of Physics, University of Babylon, College of Education for Pure Sciences, Babylon, Iraq
  • Najah M. L. Al Maimuri Building and Construction Technologies Engineering Department, College of Engineering and Engineering Technologies, Al-Mustaqbal University, 51001, Babylon, Iraq
  • Ahmed Hashim Department of Physics, University of Babylon, College of Education for Pure Sciences, Babylon, Iraq
  • Mohammed H. Abbas Department of Physics, University of Babylon, College of Education for Pure Sciences, Babylon, Iraq
  • Aseel Hadi Department of Ceramic and Building Materials, College of Materials Engineering, University of Babylon, Babylon, Iraq
  • Hamed Ibrahim Al-Zahraa University for Women, Kerbala, Iraq

DOI:

https://doi.org/10.48048/tis.2025.10534

Abstract

The present work aims to fabricate of chitosan doped with SnO2-ZnO nanoparticles to employ in various optical and electronics applications. The study included the compact of (SnO2/ZnO) nanocomposites on optical features of chitosan to be used in variety of optics and electronics applications. The chitosan-SnO2/ZnO nanocomposites have been prepared by utilizing casting technique with various concentrations of (SnO2/ZnO) nanoparticles and chitosan. The optical features have been investigated at a range of wavelengths from (320 - 920 nm). The analysis reveal that when (SnO2/ZnO) nanoparticles ratio has been increased, absorption value of chitosan-(SnO2/ZnO) nanocomposites was boosted whereas the transmittance value was drop down. Whenever (SnO2/ZnO) nanocomposites ratio have been rise, the band gap was reduced from 3.33 to 2.9 eV for allowed transition and from 3.13 to 2.51 eV for forbidden transition. The other optical features of chitosan-SnO2/ZnO nanocomposites have been boosted. Finally, the outcomes of optical features reveal that the chitosan-SnO2/ZnO nanocomposites are being possible to be utilized in a variety of applications.

HIGHLIGHTS

  • Fabrication of CS/SnO2/ZnO new nanocomposites films.
  • Effect (SnO2/ZnO) NPs on optical features of chitosan.
  • The CS/SnO2/ZnO nanocomposites films included highest absorption at UV spectrum.
  • The band gap of CS was reduced from 3.33 to 2.9 eV for allowed transition and from 3.13 to 2.51 eV for forbidden transition.
  • The chitosan-SnO2/ZnO nanocomposites are being possible to be utilized in a variety of applications.

GRAPHICAL ABSTRACT

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References

A Hashim and N Hamid. Fabrication and properties of biopolymer-ceramics nanocomposites as UV-shielding for bionanoscience application. Journal of Bionanoscience 2018; 12(6), 788-791.

A Hashim, IR Agool and KJ Kadhim. Modern developments in polymer nanocomposites for antibacterial and antimicrobial applications: A review. Journal of Bionanoscience 2018; 12(5), 608-613.

AJ Kadham, D Hassan, N Mohammad and AH Ah-yasari. Fabrication of (polymer blend-magnesium oxide) nanoparticle and studying their optical properties for optoelectronic applications. Bulletin of Electrical Engineering and Informatics 2018; 7(1), 28-34.

S Anandhavelu and S Thambidurai. Effect of annealing temperature on optical and electrochemical properties of chitosan-ZnO nanostructure. Ionics 2013; 19, 903-909.

A Aouadi, D Hamada Saud, A Rebiai, A Achouri, S Benabdesselam, FM Abd El-Mordy, P Pohl, SF Ahmad, SM Attia, HS Abulkhair, A Ararem and M Messaoudi. Introducing the antibacterial and photocatalytic degradation potentials of biosynthesized chitosan, chitosan-ZnO, and chitosan-ZnO/PVP nanoparticles. Scientific Reports 2024; 14, 14753.

VKH Bui, D Park and YC Lee. Chitosan combined with ZnO, TiO2 and Ag nanoparticles for antimicrobial wound healing applications: A mini review of the research trends. Polymers 2017; 9(1), 21.

M Dash, F Chiellini, RM Ottenbrite and E Chiellini. Chitosan - A versatile semi-synthetic polymer in biomedical applications. Progress in Polymer Science 2011; 36(8), 981-1014.

RD Bharathi, B Ranjithkumar, V Chandarshekar and B Bhuvaneshwari. Preparation of chitosan coated zinc oxide nanocomposite for enhanced antibacterial and photocatalytic activity: As a bionanocomposite. International Journal of Biological Macromolecules 2019; 129, 989-996.

E Džunuzović, K Jeremić and JM Nedeljković. In situ radical polymerization of methyl methacrylate in a solution of surface modified TiO2 and nanoparticles. European Polymer Journal 2007; 43(9), 3719-3726.

S Fatullayeva, D Tagiyev, N Zeynalov, S Mammadova and E Aliyeva. Recent advances of chitosan-based polymers in biomedical applications and environmental protection. Journal of Polymer Research 2022; 29(7), 259.

AG Madhan, LA Begam, RV Varsha, RR Ranjithkumar and RD Bharathi. Facile synthesis and characterization of chitosan/zinc oxide nanocomposite for enhanced antibacterial and photocatalytic activity. International Journal of Biological Macromolecules 2021; 190, 259-269.

A Hadi, A Hashim and Y Al-Khafaji. Structural, optical and electrical properties of PVA/PEO/SnO2 new nanocomposites for flexible devices. Transactions on Electrical and Electronic Materials 2020; 21, 283-292.

AMES Hassen, AM El Sayed, WM Morsi and S El-Sayed. Influence of Cr2O3 nanoparticles on the physical properties of polyvinyl alcohol. Journal of Applied Physics 2012; 112(9), 093525.

KS Hemalatha, K Rukmani, N Suriyamurthy and BM Nagabhushana. Synthesis, characterization and optical properties of hybrid PVA-ZnO nanocomposite: A composition dependent study. Materials Research Bulletin 2014; 51, 438-446.

KS Hemalatha, G Sriprakash, MVN Ambika Prasad, R Damle and K Rukmani. Temperature dependent dielectric and conductivity studies of polyvinyl alcohol-ZnO nanocomposite films by impedance spectroscopy. Journal of Applied Physics 2015; 118(15), 154102.

S Heydari and M Moradi. Green synthesis of nanochitosan/bentonite/SnO2-ZnO bionanocomposite for removal of heavy metal ions and photocatalytic degradation of organic dye. Journal of Polymers and the Environment 2024; 32, 3698-3717.

HH Ibrahim, AM Abdelghany, MH Gaber and SA Ali. Optical and physical characteristics of chitosan/silver vanadate nanocomposites. Optical and Quantum Electronics 2024; 56, 435.

SA Jasim, HAJ Banimuslem, FH Alsultany, E Al-Bermany and RM Mohammed. Ammonia and nitrogen dioxide detection using ZnO/CNT nanocomposite synthesized by sol-gel technique. Journal of Sol-Gel Science and Technology 2023; 108(1), 734-741.

AF Kadhim and A Hashim. Fabrication and tuning the structural and dielectric characteristics of PS/SiO2/SrTiO3 hybrid nanostructures for nanoelectronics and energy storage devices. Silicon 2023; 15(11), 4613-4621.

A Hashim, A Hadi and MH Abbas. Synthesis and unraveling the morphological and optical features of PVP-Si3N4-Al2O3 nanostructures for optical and renewable energies fields. Silicon 2023; 15(15), 6431-6438.

A Hashim, B Mohammed, A Hadi and H Ibrahim. Synthesis and augment structural and optical characteristics of PVA/SiO2/BaTiO3 nanostructures films for futuristic optical and nanoelectronics applications. Journal of Inorganic and Organometallic Polymers and Materials 2024; 34, 611-621.

HS Abdulsalam, A Hashim and MK Mohammed. Fabrication and ameliorating the performance of PS/SiO2-Sb2O3 futuristic films for high energy storage capacitors and biomedical applications. Transactions on Electrical and Electronic Materials 2025; 26, 395-404.

HS Abdulsalam, A Hashim and MK Mohammed. Synthesis and tuning the morphological and optical features of PS/SiO2-Sb2O3 promising hybrid nanomaterials for radiation shielding and futuristic optoelectronics applications. Journal of Materials Science: Materials in Electronics 2025; 36(8), 480.

HS Abdulsalam, A Hashim and MK Mohammed. Manufacturing and enhancing the features of PS/SiO2-CeO2 nanostructures for energy storage and antimicrobials applications. Journal of Inorganic and Organometallic Polymers and Materials 2025. https://doi.org/10.1007/s10904-025-03651-5

HS Abdulsalam, A Hashim and MK Mohammed. Production and tailoring the morphological and optical features of PS/SiO2-In2O3 futuristic films for optoelectronics and radiation shielding applications. Ceramics International 2025; 51(11), 14328-14336.

AAA Ahmed, AM Al-Hussam, AM Abdulwahab and ANAA Ahmed. The impact of sodium chloride as dopant on optical and electrical properties of polyvinyl alcohol. AIMS Materials Science 2018; 5(3), 533-542.

AMA Henaish and AS Abouhaswa. Effect of WO3 nanoparticle doping on the physical properties of PVC polymer. Bulletin of Materials Science 2020; 43(1), 149.

K Mahalakshmi, V Lakshmi, SDC Anitha and R MaryJenila. Optical, structural and morphological analysis of rGO decorated CoSe2 nanocomposites. International Journal of Innovative Science Engineering & Technology 2021; 8(2), 180-192.

G Santhosh, GP Nayaka, BS Madhukar and Siddaramaiah. Optical properties of PVP/Li3GaO3 nanocomposites. Materials Today: Proceedings 2017; 4, 12061-12069.

PO Amin, KA Ketuly, SR Saeed, FF Muhammadsharif, MD Symes, A Paul and K Sulaiman. Synthesis, spectroscopic, electrochemical and photophysical properties of high band gap polymers for potential applications in semi-transparent solar cells. BMC Chemistry 2021; 15, 25.

AO Salohub, AA Voznyi, OV Klymov, NV Safryuk, DI Kurbatov and AS Opanasyuk. Determination of fundamental optical constants of Zn2SnO4 films. Semiconductor Physics, Quantum Electronics & Optoelectronics 2017; 20(1), 79-84.

S Kumar, F Ye, B Mazinani, S Dobretsov and J Dutta. Chitosan nanocomposite coatings containing chemically resistant ZnO-SnO2 core-shell nanoparticles for photocatalytic antifouling. International Journal of Molecular Sciences 2021; 22(9), 4513.

Z Sattar and A Hashim. Quaternary PMMA-PEG/SnO2-sic nanocomposite films for flexible nanodielectric and energy storage applications. Silicon 2025; 17, 1681-1692.

Z Sattar and A Hashim. Synthesis of PMMA/PEG/SiO2/SiC multifunctional nanostructures and exploring the microstructure and dielectric features for flexible nanodielectric applications. Silicon 2024; 16, 6181-6192.

G Ahmed and A Hashim. Synthesis of PMMA/PEG/Si3N4 nanostructures and exploring the structural and dielectric characteristics for flexible nanoelectronics applications. Silicon 2023; 15, 3977-3985.

H Jaafar, A Hashim and BH Rabee. Tailoring the influence of hybrid SiC/SrTiO3 nanomaterials doped PMMA/PEO for promising nanodielectric and nanoelectronic applications. Silicon 2023; 16(5), 1905-1915.

HK Jaafar, A Hashim and BH Rabee. Fabrication and unraveling the morphological, structural, and dielectric features of PMMA-PEO-SiC-BaTiO3 promising quaternary nanocomposites for multifunctional nanoelectronics applications. Journal of Materials Science: Materials in Electronics 2024; 35(2), 128.

A Kareem, A Hashim and HB Hassan. Ameliorating and tailoring the morphological, structural, and dielectric features of Si3N4/CeO2 futuristic nanocomposites doped PEO for nanoelectronic and nanodielectric applications. Journal of Materials Science: Materials in Electronics 2024; 35(7), 461.

MMH Lin, YH Wang, CH Kuo, SF Ou, PZ Huang, TY Song, YC Chen, ST Chen, CH Wu, YH Hsueh and FY Fan. Hybrid ZnO/chitosan antimicrobial coatings with enhanced mechanical and bioactive properties for titanium implants. Carbohydrate Polymers 2021; 257, 117639.

MH Abbas, H Ibrahim, A Hashim and A Hadi. Ameliorating and tailoring the features of silica-silicon carbide nanoceramic doped polyethylene oxide for promising optoelectronics applications. Silicon 2025; 17, 697-707.

A Hashim, G Ahmed, H Ibrahim and A Hadi. Ameliorating the features of TiN/SiO2 promising nanoceramic doped optical polymer for multifunctional optoelectronics applications. Silicon 2025; 17, 585-598.

AF Kadhim, G Ahmed and A Hashim. Fabrication and tuning the structural and optical features of SiO2/ Si3N4 nanomaterials doped PS for promising optoelectronics applications. Journal of Inorganic and Organometallic Polymers and Materials 2024; 34(9), 4267-4276.

Z Sattar and A Hashim. Fabrication and characteristics of PMMA-PEG/SiO2-SiC quaternary nanocomposites for gamma ray shielding and flexible optoelectronics applications. Journal of Materials Science: Materials in Electronics 2024; 35(24), 1660.

HK Jaafar, A Hashim and BH Rabee. Fabrication and tuning the morphological and optical characteristics of PMMA/PEO/SiC/BaTiO3 newly quaternary nanostructures for optical and quantum electronics fields. Optical and Quantum Electronics 2023; 55(11), 989.

HK Jaafar, A Hashim and BH Rabee. Synthesis and boosting the morphological and optical characteristics of SiC/SrTiO3 nanomaterials doped PMMA/PEO for tailored optoelectronics fields. Silicon 12024; 6, 603-614.

A Hassen, S El-Sayed, WM Morsi and AM El Sayed. Preparation, dielectric and optical properties of Cr2O3/PVC nanocomposite films. Journal of Advances in Physics 2024; 4(3), 571-584.

Z Sattar and A Hashim. Fabrication of PMMA/PEG/SnO2/SiC quaternary multifunctional nanostructures and exploring the microstructure and optical features for radiation attenuation and flexible photonics applications. Journal of Materials Science: Materials in Electronics 2015; 35(31), 2015.

A Kareem, A Hashim and HB Hassan. Synthesis and boosting the morphological, structural and optical features of PEO/Si3N4/CeO2 promising nanocomposites films for futuristic nanoelectronics applications. Silicon 2024; 16, 2827-2838.

A Hazim, A Hashim and H Abduljalil. Fabrication of novel (PMMA-Al2O3/Ag) nanocomposites and its structural and optical properties for lightweight and low cost electronics applications. Egyptian Journal of Chemistry 2021; 64(1), 359-374.

A Hashim, H Ibrahim and A Hadi. Fabrication and augmentation of optical and structural characteristics of PVA/SiC/CoFe2O4 hybrid nanocomposites for tailored optical and quantum electronics applications. Optical and Quantum Electronics 2024; 56, 1177.

A Atta, MM Abdelhamied, AM Abdelreheem and MR Berber. Flexible methyl cellulose/polyaniline/silver composite films with enhanced linear and nonlinear optical properties. Polymers 2021; 13(8), 1225.

A Hashim, H Ibrahim, FL Rashid and A Hadi. Synthesis and augmented morphological and optical properties of Si3N4-TiN inorganic nanostructures doped PVP for promising optoelectronics applications. Journal of Inorganic and Organometallic Polymers and Materials 2025; 35(2), 827-837.

A Hashim, SM Alshrefi, HH Abed and A Hadi. Synthesis and boosting the structural and optical characteristics of PMMA/SiC/CdS hybrid nanomaterials for future optical and nanoelectronics applications. Journal of Inorganic and Organometallic Polymers and Materials 2024; 34(2), 703-711.

A Hashim, A Kareem and H Ibrahim. Production and ameliorating the characteristics of (SiO2-CdS) futuristic nanoceramic doped optical material for flexible nanoelectronics applications. Silicon 2025; 17, 517-530.

S Salman, N Bakr and MH Mahmood. Preparation and study of some optical properties of (PVA-Ni (CH3COO)2) composites. International Journal of Current Research 2014; 6(11), 9638-9643.

AA Muhmood, IA Zgair, MA Hussein, LH Mahdi, BS Jabbar and AHO Alkhayatt. Preparation and optical characterizations of PVA: Ag nano composite. Journal of Physics: Conference Series 2021; 1879(3), 032083.

H Ahmed and A Hashim. Design and tailoring the structural and spectroscopic characteristics of Sb2S3 nanostructures doped PMMA for flexible nanoelectronics and optical fields. Optical and Quantum Electronics 2023; 55(3), 280.

A Hazim, HM Abduljalil and A Hashim. Design of PMMA doped with inorganic materials as promising structures for optoelectronics applications. Transactions on Electrical and Electronic Materials 2021; 22, 851-868.

H Ahmed and A Hashim. Design and exploring the structure, optical and electronic characteristics of silicon doped PS/MoS2 structures for electronics Nanodevices. Optical and Quantum Electronics 2022; 54(7), 403.

H Ahmed and A Hashim. Tunable spectroscopic, electronic and thermal characteristics of PS/Nb5Si3/ZnS nanostructures for optics and potential nanodevices. Optical and Quantum Electronics 2023; 55(1), 9.

H Ahmed and A Hashim. Tuning the characteristics of novel (PVA-Li-Si3N4) structures for renewable and electronics fields. Silicon 2022; 14(8), 4079-4086.

NAH Al-Aaraji, A Hashim, HM Abduljalil and A Hadi. Tailoring the design, structure and spectroscopic characteristics of SiC/CuO doped transparent polymer for photonics and quantum nanoelectronics fields. Optical and Quantum Electronics 2023; 55(8), 743.

H Ahmed and A Hashim. Design and tailoring the optical and electronic characteristics of PS/ZnS/SiBr4 new structures for electronics nanodevices. Silicon 2023; 15(1), 83-91.

HM Gayitri, M Al-Gunaid and APG Prakash. Optical, structural and thermal properties of hybrid PVA/CaAl2ZrO6 nanocomposite films. Indian Journal of Engineering & Materials Sciences 2020; 27, 320-332.

NS Alghunaim. Spectroscopic analysis of PMMA/PVC blends containing CoCl2. Results in Physics 2015; 5, 331-336.

S Sabbah, M Hasan, B Yehiaa and Z Satar. The effect of metal powder on the optical properties of polyvinyl acetate. Journal of Advance Research in Applied Science 2016; 3(1), 1-6.

HB Hassan, A Hashim and HM Abduljalil. Synthesis, structural and optical characteristics of PEO/NiO/In2O3 hybrid nanomaterials for photodegradation of pollutants from wastewater. Optical and Quantum Electronics 2023; 55, 556.

HB Hassan, A Hashim and HM Abduljalil. Tailoring structural, optical characteristics of CuO/In2O3 nanoparticles-doped organic material for photodegradation of dyes pollutants. Polymer Bulletin 2023; 80, 9059-9075.

HAJ Hussien, RG Kadhim and A Hashim. Investigating the low cost photodegradation performance against organic Pollutants using CeO2/MnO2/ polymer blend nanostructures. Optical and Quantum Electronics 2022; 54(11), 704.

FA Jasim, A Hashim, AG Hadi, F Lafta, SR Salman and H Ahmed. Preparation of (pomegranate peel-polystyrene) composites and study their optical properties. Research Journal of Applied Sciences 2013; 8(9), 439-441.

YM Jawad, MFH Al-Kadhemy and JAS Salman. Synthesis structural and optical properties of CMC/MgO nanocomposites. Materials Science Forum 2021; 1039, 104-114.

HAJ Hussien and A Hashim. Fabrication and analysis of PVA/TiC/SiC hybrid nanostructures for nanoelectronics and optics applications. Journal of Inorganic and Organometallic Polymers and Materials 2024; 34, 2716-2727.

A Hashim, A Hadi, H Ibrahim and FL Rashid. Fabrication and boosting the morphological and optical properties of PVP/SiC/Ti nanosystems for tailored renewable energies and nanoelectronics fields. Journal of Inorganic and Organometallic Polymers and Materials 2024; 34(4), 1678-1688.

MH Abbas, H Ibrahim, A Hashim and A Hadi. Fabrication and tailoring structural, optical, and dielectric properties of PS/CoFe2O4 nanocomposites films for nanoelectronics and optics applications. Transactions on Electrical and Electronic Materials 2024; 25, 449-457.

A Hashim, HH Abed and SM Alshrefi. Ameliorating and tuning the structural, morphological, and optical characteristics of chromium oxide/silicon carbide promising hybrid nanocomposites doped PMMA for futuristic nanoelectronics and photonics applications. Silicon 2024; 16(12), 5087-5095.

V Sangawar and M Golchha. Evolution of the optical properties of polystyrene thin films filled with zinc oxide nanoparticles. International Journal of Scientific & Engineering Research 2013; 4(6), 2700-2705.

S Agarwal and VK Saraswat. Structural and optical characterization of ZnO doped PC/PS blend nanocomposites. Optical Materials 2015; 42, 335-339.

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Published

2025-07-15