Thermal and Microstructural Characterization of the Multicomponent Alloy Al33wt%Cu1wt%Ni-1.2wt%Ta Solidified with Transient Heat Flow

Authors

  • Wellington Jesus Mechanical Engineering Post-Graduation Program, Universidade Federal do Pará, Belém, Brazil
  • Vinicius Silva Mechanical Engineering Post-Graduation Program, Universidade Federal do Pará, Belém, Brazil
  • Héricles Souza Mechanical Engineering Post-Graduation Program, Universidade Federal do Pará, Belém, Brazil
  • Thiago Costa Federal Institute of Education, Science and Technology of Pará, Belém, Brazil
  • Otávio Rocha Federal Institute of Education, Science and Technology of Pará, Belém, Brazil
  • Luiz Nascimento Federal Institute of Education, Science and Technology of Pará, Belém, Brazil
  • Adrina Silva Mechanical Engineering Post-Graduation Program, Universidade Federal do Pará, Belém, Brazil

DOI:

https://doi.org/10.48048/tis.2024.8029

Keywords:

Solidification, Thermal characterization, Intermetallic phase, Kinetics, Columnar grains, Secondary dendrite arm spacing

Abstract

The demand for materials with specific properties continues to grow in modern industry, necessitating a deeper understanding of metal solidification processes. This study investigates the thermal and microstructural characteristics of a novel multicomponent alloy, Al33wt%Cu1wt%Ni-1.2wt%Ta, which has not been previously reported in the literature. This alloy, comprising aluminum, copper, nickel and tantalum, exhibits superior mechanical strength, thermal stability and corrosion resistance compared to conventional alloys, making it suitable for various applications. Utilizing transient heat flow techniques, thermal characterization and microstructural analysis were performed on the alloy after solidification. Thermal mapping revealed variable growth and cooling rates along the ingot, influencing macrostructural transitions from columnar to equiaxed grains. Microstructural examination uncovered a complex evolution, with refined dendritic spacings initially, followed by the formation of intermetallic phases such as Al3Ta, α-Al and Al2Cu. The study also proposed a hypothesis on the formation of diamond-shaped intermetallics like Ni3Ta and Ta(Cu,Al)2, which were consumed to form Al7Cu4Ni at the edges. Secondary dendritic spacing analysis supported this hypothesis, showing correlation with growth laws. The findings provide valuable insights into solidification behavior and microstructural evolution, aiding in parameter optimization and enhancing the alloy’s properties for specific applications. However, limitations include the need for further research to explore mechanical and thermal properties and validate industrial potential.

HIGHLIGHTS

  • This study introduces a novel investigation into the Al33wt%Cu1wt%Ni-1.2wt%Ta alloy composition, filling a gap in existing literature and offering new insights into the thermal and microstructural characteristics of this multicomponent alloy.
  • The study evaluates the thermal, macro and microstructural properties of a solidified alloy using a transient solidification device, offering valuable insights for industrial applications. Despite diverging from traditional literature methods of producing this alloy, its practical relevance lies in the use of a widely adopted production technique, making its findings applicable to industry.
  • The study predominantly focuses on solidification kinetics and macro/microstructural characterization, limiting exploration into other mechanical and thermal properties.

GRAPHICAL ABSTRACT

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References

X Su, H Qu, Y Lei, R Hou, Y Cao, D Siddique, Z Qi, G Shen and X Fan. Influence of Ni on the microstructures and mechanical properties of heat-treated Al-Cu-Ce-Mn-Zr alloys. Crystals 2023; 13, 380.

KS Tun, A Kumar and M Gupta. Introducing a high performance Mg-based multicomponent alloy as an alternative to Al-alloys. Front. Mater. 2019; 6, 215.

D Kim, K Kim and H Kwon. Interdiffusion and intermetallic compounds at Al/Cu interfaces in Al-50vol.%Cu composite prepared by solid-state sintering. Materials 2021; 14, 4307.

E Correa, E Militão, F Costa, I Ferreira and O Rocha. Solidification thermal parameters, microstructural evolution and dendritic growth in an AlCuNi alloy. Phil. Mag. Lett. 2021; 101, 21-9.

S Saud, E Hamzah, H Bakhsheshi-Rad and T Abubakar. Effect of Ta additions on the microstructure, damping, and shape memory behaviour of prealloyed Cu-Al-Ni shape memory alloys. Scanning 2017; 2017, 178945.

Y Zhou, B Wen, Y Ma, R Melnik and X Liu. First-principles studies of Ni-Ta intermetallic compounds. J. Solid State Chem. 2012; 187, 211-8.

R Kakitani, G Gouvea, A Garcia, N Cheun and J Spinelli. Thermal analysis during solidification of an Al-Cu eutectic alloy: Interrelation of thermal parameters, microstructure and hardness. J. Therm. Anal. Calorimetry 2019; 137, 983-96.

C Suryanarayana. Mechanical alloying and milling. Progr. Mater. Sci. 2001; 46, 1-184.

C Suryanarayana. Mechanical alloying: A novel technique to synthesize advanced materials - a review. J. Mater. Sci. Tech. 2018; 34, 177-96.

J Andersson, T Helander, L Höglund, P Shi and B Sundman. Thermo-Calc and DICTRA, computational tools for materials science. Calphad 2002; 26, 273-312.

D Braga, M Júnior, S Araújo and L Nascimento. Processo de fabricação das ligas Al-5%Cu e Al-5%Cu-1%Ni com solidificação em regime transiente de fluxo de calor, análise da microestrutura e dureza. Instituto Scientia 2022; 3, 274-91.

A Barros, C Cruz, AP Silva, N Cheung, A Garcia, O Rocha and A Moreira. Length scale of solidification microstructure tailoring corrosion resistance and microhardness in T6 heat treatment of an Al-Cu-Mg alloy. Corrosion Eng. Sci. Tech. 2020; 55, 471-9.

T Costa, M Dias, C Silva, E Freitas, AP Silva, N Cheung and A Garcia. Measurement and interrelation of length scale of dendritic microstructures, tensile properties, and machinability of Al-9 wt% Si-(1 wt% Bi) alloys. Int. J. Adv. Manuf. Tech. 2019; 105, 1391-410.

I Magno, F Souza, T Costa, J Nascimento, AP Silva and O Rocha. Interconnection between the solidification and precipitation hardening processes of an AlSiCu alloy. Mater. Sci. Tech. 2019; 35, 791-806.

H Kaya, E Çadırlı, M Gunduz and A Ülgen. Effect of the temperature gradient, growth rate, and the interflake spacing on the microhardness in the directionally solidified Al-Si eutectic alloy. J. Mater. Eng. Perform. 2003; 12, 544-51.

C Siqueira, N Cheung and A Garcia. The columnar to equiaxed transition during solidification of Sn-Pb alloys. J. Alloy. Comp. 2003; 351, 126-34.

C Gomes, R Hideo, A Barros, J Silva, AP Silva, A Moreira and O Rocha. On the natural convection in the columnar to equiaxed transition in directionally solidified aluminum-based binary and multicomponent alloys. Mater. Res. 2015; 18, 1362-71.

H Fredriksson and T Nylen. Mechanism of peritectic reactions and transformations. Met. Sci. 1982; 16, 283-94.

H Kerr and W Kurz. Solidification of peritectic alloys. Int. Mater. Rev. 1996; 41, 129-64.

J Dshemuchadse, S Bigler, A Simonov, T Weber and W Steurer. A new complex intermetallic phase in the system Al-Cu-Ta with familiar clusters and packing principles. Acta Crystallogr. B Struct. Crystallogr. Cryst. Chem. 2013; B69, 238-48.

H Nowotny and H Oesterreicher. Die kristallstrukturen von - TaNi3, Ta(Cu,Al)2, Nb(Cu,Al)2 und Ta6(Cu,Al)7. Monatshefte Chemie 1964; 95, 982-9.

J Davim. Introduction to mechanical engineering. Springer Cham, Netherlands, 2018.

M Aghahadi, M Niknejadi and D Toghraie. An experimental study on the rheological behavior of hybrid Tungsten oxide (WO3)-MWCNTs/engine oil Newtonian nanofluids. J. Mol. Struct. 2019; 1197, 497-507.

S Yan, D Toghraie, L Abdulkareem, A Alizadeh, P Barnoon and M Afrand. The rheological behavior of MWCNTs-ZnO/Water-Ethylene glycol hybrid non-Newtonian nanofluid by using of an experimental investigation. J. Mater. Res. Tech. 2020; 9, 8401-6.

S Tian, N Arshad, D Toghraie, S Eftekhari and M Hekmatifar. Using perceptron feed-forward Artificial Neural Network (ANN) for predicting the thermal conductivity of graphene oxide-Al2O3/water-ethylene glycol hybrid nanofluid. Case Stud. Therm. Eng. 2021; 26, 101055.

B Ruhani, M Andani, A Abed, N Sina, G Smaisim, S Hadrawi and D Toghraie. Statistical modeling and investigation of thermal characteristics of a new nanofluid containing cerium oxide powder. Heliyon 2022; 8, 11373.

A Mosavi, M Hekmatifar, A Alizadeh, D Toghraie, R Sabetvand and A Karimipour. The molecular dynamics simulation of thermal manner of Ar/Cu nanofluid flow: The effects of spherical barriers size. J. Mol. Liq. 2020; 319, 114183.

J Davim. Modern mechanical engineering. Springer, Berlin, Germnay, 2014.

O Rocha, C Siqueira and A Garcia. Heat flow parameters affecting dendrite spacings during unsteady-state solidification of Sn-Pb and Al-Cu alloys. Metall. Mater. Trans. 2003; 34, 995-1006.

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Published

2024-07-19

Issue

Vol. 21 No. 9 (2024): Trends in Sciences, Volume 21, Number 9, September 2024

Section

Research Articles

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