Photocatalysis-Assisted Process of Reusable PVA/TiO2 Nanofibers

Authors

  • Ahmad Kusumaatmaja Department of Physics, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia
  • Ari Dwi Nugraheni Department of Physics, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia
  • Diki Purnawati Department of Physics, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia
  • Ani Rohmatillah Department of Physics, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia
  • Dian Nur Mahardika Department of Physics, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia

DOI:

https://doi.org/10.48048/tis.2024.7772

Keywords:

Harsh pH, Nanofibers, Photocatalysis-assisted, PVA, TiO2

Abstract

Photocatalysis-assisted PVA/TiO2 nanofibers has become a prospective technology for water filtration applications. In line with this application, swelling behavior, photocatalytic activity and reusability are crucial considerations. This work presents the evaluation of swelling behavior and photocatalytic activity of PVA/TiO2 nanofibers in harsh pH environment. By varying pH environment at pH = 1 - 12, we have successfully shown that pH = 7 is the best environment for the PVA/TiO2 nanofibers-based water filtration. On this environment, the nanofibers has 92 % degradability and is able to resist Methylene Blue (MB) solution for up to 5 min. Likewise, it shows excellent reusability over 5 cycles usage. Moreover, the nanofibers is prospective for rapid filtration in harsh pH environment. This work is a step forward toward environmental-friendly water filtration in harsh pH environment.

HIGHLIGHTS

  • Study of photocatalysis-assisted PVA/TiO2 nanofibers for environmental-friendly water filtration.
  • Discover superb degradability up to 98 % within 5 min application in Methylene Blue solution.
  • Perform superior reusability up to 5 cycles usage.
  • Highly prospective for harsh pH environment water filtration.

GRAPHICAL ABSTRACT

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Author Biography

Ani Rohmatillah , Department of Physics, Universitas Gadjah Mada, Yogyakarta 55281, Indonesia

Department of Physics

References

DD Ratnayaka, MJ Brandt and KM Jhonson. Chapter 6 - chemistry, microbiology and biology of water. Water Supply 2009, https://doi.org/10.1016/B978-0-7506-6843-9.00014-7.

HI Gomes, WM Mayes, M Rogerson, DI Stewart and IT Burke. Alkaline restudies and environment: A review of impacts, management practices and opportunities. J. Cleaner Prod. 2016; 112, 3571-82.

DN Mahardika. 2019, Effect of basic pH on swelling capability and photocatalysis of PVA/TiO2 composite. Undergraduate Thesis. Universitas Gadjah Mada, Yogyakarta, Indonesia.

A Rohmatillah. 2019, Photocatalys ability of composite polyvinyl alcohol/ titanium dioxide (TiO2) in acid condition. Undergraduate Thesis. Universitas Gadjah Mada, Yogyakarta, Indonesia.

Y Deng and R Zhao. Advanced oxidation processes (AOPs) in wastewater treatment. Curr. Pollut. Rep. 2015; 1, 167-76.

H Zangeneh, AAL Zinatizadeh, M Habibi, M Akia and MH Isa. Photocatalytic oxidation of organic dyes and pollutants in wastewater using different modified titanium dioxides: A comparative review. J. Ind. Eng. Chem. 2015; 26, 1-36.

ADS Montallana, BZ Lai, JP Chu and MR Vasquesz. Enhancement of photodegradation efficiency of PVA/TiO2 nanofiber composites via plasma treatment. Mater. Today Comm. 2020; 24, 101183.

MA Shaheed and FH Hussein. Preparation and applications of titanium dioxide and zinc oxide nanoparticles. J. Environ. Anal. Chem. 2015; 2, e109.

Nasikhudin, M Diantoro, A Kusumaatmaja and K Triyana. Enhancing photocatalytic performance by sonication and surfactant addition on the synthesis process of PVA/TiO2 nanofibers membranes by electrospinning method. AIP Conf. Proc. 2020; 2251, 40045.

CG Lee, H Javed, D Zhang, JH Kim, P Westerhoff, Q Li and PJJ Alvarez. Porous electrospun fibers embedding TiO2 for adsorption and photocatalytic degradation of water pollutants. Environ. Sci. Tech. 2018; 52, 4285-93.

X Qu, PJJ Alvarez and Q Li. Application of nanotechnology in water and wastewater treatment. Water Res. 2013; 47, 3931-46.

F Loosli, L Vitorazi, JF Berret and S Stoll. Towards a better understanding on agglomeration mechanisms and thermodynamic properties of TiO2 nanoparticles interacting with natural organic matter. Water Res. 2015; 80, 139-48.

M Nasr, L Soussan, R Viter, C Eid, R Habchi, P Miele and M Bechelany. High photodegradation and antibacterial activity of BN-Ag/TiO2 composite nanofibers under visible light. New J. Chem. 2018; 42, 1250-9.

AA Nada, M Nasr, R Viter, P Miele, S Roualdes and M Bechelany. Mesoporous ZnFe2O4@TiO2 nanofibers prepared by electrospinning coupled to PECVD as Highly performing photocatalytic materials. J. Phys. Chem. C 2017; 121, 24669-77.

M Nasr, S Balme, C Eid, R Habchi, P Miele and M Bechelany. enhanced visible-light photocatalytic performance of electrospun rGO/TiO2 composite nanofibers. J. Phys. Chem. C 2017; 121, 261-9.

AH Mamaghani, F Haghighat and CS Lee. Role of titanium dioxide (TiO2) structural design/morphology in photocatalytic air purification. Appl. Catal. B Environ. 2020; 269, 118735.

CI Covaliu-Mierla, E Matei, O Stoian, L Covalia, AC Constandanche, H Iovu and G Paraschiv. TiO2-based nanofibrous membranes for environmental protection. Membranes 2022; 12, 236.

Nasikhudin, EP Ismaya, M Diantoro, A Kusumaatmaja and K Triyana. Preparation of PVA/TiO2 composites nanofibers by using electrospinning method for photocatalytic degradation. IOP Conf. Ser. Mater. Sci. Eng. 2017; 202, 12011.

JH Yeo, M Kim, H Lee, J Cho and J Park. Facile and novel eco-friendly poly (vinyl alcohol) nanofilters using the photocatalytic property of titanium oxide. ACS Omega 2020; 5, 5026-33.

X Zhou, B Liu, Y Chen, L Guo and G Wei. Carbon nanofiber-based three-dimensional nanomaterials for energy and environmental applications. Mater. Adv. 2020; 1, 2163-81.

R Gopal, S Kaur, Z Ma, C Chan, S Ramakrishna and T Matsuura. Electrospun nanofibrous filtration membrane. J. Membr. Sci. 2006; 281, 581-6.

MFD Riccardis. Electrospun nanofibrous membrane for air filtration: A critical review. Compounds 2023; 3, 390-410.

CH He and J Gong. The preparation of PVA-Pt/TiO2 composite nanofiber aggregate and the photocatalytic degradation of solid-phase polyvinyl alcohol. Polymer Degrad. Stabil. 2003; 81, 117-24.

YJ Nien, PJ Lin, LY Wu, TH Liou and PI Wey. Preparation of poly (vinyl alcohol)/TiO2 nanofibers by electrospinning. In: Proceedings of the 4th Tropical Conference on Nanoscale Science and Engineering Forum, American Institute of Chemical Engineers, Texas. 2004.

K Garg and GL Bowlin. Electrospining jets and nanofibrous structures. Biomicrofluidics 2011; 30, 13403.

S Pourjafar, A Rahimpour and M Jahanshahi. Synthesis and characterization of PVA/PES thin film composites nanofiltration membrane modified with TiO2 nanoparticles for better performance and surface properties. J. Ind. Eng. Chem. 2012; 18, 1398-405.

M Sadeghi and M Yarahmadi. Swelling kinetics study of hydrolyzed starch-poly acrylonitrile superabsorbent hydrogel with salt-sensitivity properties. Asian J. Chem. 2011; 23, 5225-8.

F Ganji, FS Vasheghani and FE Vaseghani. Theoretical descriptions of hydrogel swelling: A review. Iranian Polymer J. 2010; 19, 375-98.

ESM Cardona, JR Camargo and YAC Monsalve. A review of polyvinyl alcohol derivatives: Promising materials for pharmaceutical and biomedical applications. Afr. J. Pharm. Pharmacol. 2014; 8, 674-84.

J Wang, W Wu and Z Lin. Kinetics and thermodynamics of the water sorption of 2-hydroxethyl methacrylate/styrene copolymer hydrogels. J. Appl. Polymer Sci. 2008; 109, 3018-23.

J Schneider, M Matsuoka, M Takeuchi, J Zhang, Y Horiuchi, M Anpo and DW Bahnemann. Understanding TiO2 photocatalysis: Mechanisms and materials. Chem. Rev. 2014; 114, 9919-86.

SS Hemdan. The shift in the behavior of methylene blue toward the sensitivity of medium: Solvatochromism, solvent parameters, regression analysis and investigation of cosolvent on the acidity constants. J. Fluorescence 2023; 33, 2489-502.

Nasikhudin, M Diantoro, A Kusumaatmaja and K Triyana. Study on photocatalytic properties of TiO2 nanoparticle in various pH condition. J. Phys. Conf. Ser. 2018; 1011, 12069.

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Published

2024-05-20

How to Cite

Kusumaatmaja, A. ., Nugraheni, A. D. ., Purnawati, D. ., Rohmatillah , A. ., & Nur Mahardika, D. . (2024). Photocatalysis-Assisted Process of Reusable PVA/TiO2 Nanofibers . Trends in Sciences, 21(7), 7772. https://doi.org/10.48048/tis.2024.7772