Effect of Thickness on Electrical and Optical Properties of ZnO:Al Films

Authors

  • Thawatchai Chanthong Department of Physics, Faculty of Science and Technology, Phuket Rajabhat University, Phuket 83000, Thailand
  • Weerawat Intaratat Department of Physics, Faculty of Science and Technology, Phuket Rajabhat University, Phuket 83000, Thailand
  • Thanate Na Wichean Department of Materials Engineering, Faculty of Engineering, Kasetsart University, Bangkok 10900, Thailand

DOI:

https://doi.org/10.48048/tis.2023.6372

Keywords:

ZnO films, Electrical resistivity, Optical properties

Abstract

Zinc oxide (ZnO:Al) films were prepared on a substrate of different thicknesses by sputtering at 1×10−2 mbar argon gas pressure and 200 W power. The effect of film thickness on the structural, electrical, and optical properties was investigated by X-ray diffraction (XRD), 4-point probe technique, and ultraviolet-visible spectroscopy. The XRD film crystal structure study revealed that all sample films at thicknesses of 66, 106, 150 and 193 nm, respectively, exhibited planar Hexagonal wurtzite crystal structure (002), and ZnO crystals were grown along the c-axis. The ZnO:Al film at a thickness of 66 nm had the highest strain and the smallest crystal size compared to other films. The electrical resistivity decreases with increasing film thickness. The sample at 193 nm has the lowest resistivity (1.37 Ω.m). The results showed that light transmission revealed that all sample films had high transparency in the white and near-UV region at a wavelength of 350 to 800 nm, with an average light transmittance shift of 85 - 95 %. The energy band gap increased with the film thickness of 3.49(66 nm), 3.55(106 nm), and 3.59(150 nm) eV, and decreased to 3.57 eV at 193 nm, respectively.

HIGHLIGHTS

  • The different thicknesses Zinc oxide (ZnO:Al) films were prepared by sputtering at 1×10-2 mbar argon gas pressure and 200 W power was used to study the effect of film thickness on the structural, electrical, and optical properties
  • The electrical resistivity changing of ZnO:Al film depends on the film thickness. The electrical resistivity is reduced with increasing ZnO:Al film thickness
  • The ZnO:Al film are highlighted by their characteristics for light transmission at the wavelengths between 350 and 800 nm, and exhibited exceptional transparency in the white and near-UV range


GRAPHICAL ABSTRACT

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References

V Parihar, M Raja and R Paulose. A brief review of structural, electrical and electrochemical properties of zinc oxide nanoparticles. Rev. Adv. Mater. Sci. 2018; 53, 119-30.

A Moezzi, AM McDonagh and MB Cortie. Zinc oxide particles: Synthesis, properties and applications. Chem. Eng. J. 2012; 185-186, 1-22.

A Alarabi, Z Zeng, Y Gao, S Gao, S Jiao, D Wang and J Wang. Influence of different substrates on ZnO nanorod arrays properties. Solid State Sci. 2018; 85, 21-5.

A Deachana, PK Chu and D Boonyawan. ZnO nanorod synthesis via controlled ZnO seed layer by filtered pulse cathodic vacuum arc: Luminescence enhancement. Adv. Mater. Res. 2013; 802, 1-6.

BA Farsi, TM Souier, FA Marzouqi, MA Maashani, M Bououdina, HM Widatallah and MA Abri. Structural and optical properties of visible active photocatalytic Al doped ZnO nanostructured thin films prepared by dip coating. Opt. Mater. 2021; 113, 110868.

NH Erdogan, T Sedefoglu and H Kavak. Effect of Na doping on microstructures, optical and electrical properties of ZnO thin films grown by sol-gel method. J. Alloys Compounds 2021; 881, 160554.

Y Ammaih, A Lfakir, B Hartiti, A Ridah, P Thevenin and M Siadat. Structural, optical and electrical properties of ZnO:Al thin films for optoelectronic applications. Opt. Quantum Electr. 2014; 46, 229-34.

AH Hammad, MS Abdel-Wahab, S Vattamkandathil and AR Ansari. Structural and optical properties of ZnO thin films prepared by RF sputtering at different thicknesses. Phys. B Cond. Matter 2018; 540, 1-8.

LP Dai, H Deng, EY Mao and JD Zang. The recent advances of research on p-type ZnO thin film. J. Mater. Sci. Mater. Electr. 2008; 19, 727-34.

G Malik, S Mourya, J Jaiswal and R Chandra. Effect of annealing parameters on optoelectronic properties of highly ordered ZnO thin films. Mater. Sci. Semiconduct. Proc. 2019; 100, 200-13.

AK Jazmati and B Abdallah. Optical and structural study of ZnO thin films deposited by RF magnetron sputtering at different thickness: a comparison with single crystal. Mater. Res. 2018; 21, 1-6.

SS Shariffudin, M Salina and SH Herman. Effect of films thickness on structural, electrical and optical properties of sol-gel deposited layer-by-layer ZnO nanoparticles. Tran. Ele. Electr. Mater. 2012; 13, 102-5.

M Baradaran, FE Ghodsi, C Bittencourt and E llobet. The role of Al concentration on improving the photocatalytic performance of nanostructured ZnO/ZnO:Al/ZnO multilayer thin films. J. Alloys Compounds 2019; 788, 289-301.

G Yergaliuly, B Soltabayev, S Kalybekkyzy, Z Bakenov and A Mentbayeva. Effect of thickness and reaction media on properties of ZnO thin films by SILAR. Sci. Rep. 2022; 12, 851.

MR Islam, M Rahman, SFU Farhad and J Podder. Structural, optical and photocatalysis properties of sol-gel deposition Al-doped ZnO thin films. Surfaces Inter. 2019; 16, 120-6.

N Nagayasamy, S Gandhimathination and V Veerasamy. The effect of ZnO thin film and its structural and optical properties prepared by sol-gel spin coating method. Open J. Met. 2013; 3, 8-11

R Pérez-Cuapio, M Pacio, H Juárez, JA Alvarado, C Guarneros, C Bueno and A Pacio. Effect of ZnO film thickness on its optical and structural properties. J. Nano Res. 2018; 52, 102-14.

BA Anandh, AS Ganesh, R Thangarasu, R Sakthivel, R Kannusamy and K Tamilselvan. Structure, morphological and optical properties of aluminium doped ZnO thin films by dip-coating method. Orient. J. Chem. 2018; 3, 1619-24.

T Amakali, LS Daniel, V Uahengo, NY Dzade and NHD Leeuw. Structural and optical properties of ZnO thin films prepared by molecular precursor and sol-gel methods. Crystals 2020; 10, 132.

P Ghosh and Q Tran. Correlation between bulk and surface resistivity of concrete. Int. J. Conc. Struct. Mater. 2014; 9, 119-32.

A Ismail and MJ Abdullah. The structural and optical properties of ZnO thin films prepared at different RF sputtering power. J. King Saud Univ. Sci. 2013; 25, 209-15.

BZ Dong and GJ Fang. Effect of thickness on structural, electrical, and optical properties of ZnO:Al films deposited by pulsed laser deposition. J. Appl. Phys. 2007; 101, 033713.

KG Saw, NM Aznan, FK Yam, SS Ng and SY Pung. New insights on the burstein-moss shift and band gap narrowing in indium-doped zinc oxide thin films. PLoS One 2015; 10, e0141180.

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Published

2023-01-18

How to Cite

Chanthong, T. ., Intaratat, W. ., & Na Wichean, T. . (2023). Effect of Thickness on Electrical and Optical Properties of ZnO:Al Films . Trends in Sciences, 20(3), 6372. https://doi.org/10.48048/tis.2023.6372