Chasew (Anacardium Occidentale) Leaves Extract as Green Corrosion Inhibitor of API 5L X52 in Acidic Media

Authors

  • Arini Nikitasari Research Center for Metallurgy, National Research and Innovation Agency, South Tangerang 15313, Indonesia
  • Ika Melya Astuti Department of Metallurgical Engineering, Faculty of Engineering, Sultan Ageng Tirtayasa University, Cilegon 42435, Indonesia
  • Siti Musabikha Research Center for Metallurgy, National Research and Innovation Agency, South Tangerang 15313, Indonesia
  • Rahayu Kusumastuti Research Center for Metallurgy, National Research and Innovation Agency, South Tangerang 15313, Indonesia
  • Siska Prifiharni Research Center for Metallurgy, National Research and Innovation Agency, South Tangerang 15313, Indonesia
  • Gadang Priyotomo Research Center for Metallurgy, National Research and Innovation Agency, South Tangerang 15313, Indonesia

DOI:

https://doi.org/10.48048/tis.2023.4733

Keywords:

API 5L X52, Cashew leaves, Green corrosion inhibitor, Adsorption, Electrochemical measurement

Abstract

Chasew leaves extract has been investigated as green corrosion inhibitor to inhibit the corrosion process of API 5L X52 in acidic media. The inhibition effect of cashew leaves was analyzed using electrochemical measurement such as Tafel Polarization and Electrochemical Impedance Spectroscopy (EIS). FTIR, polyphenol content and phytochemical analysis were also employed to ensure the chemical compound of cashew leaves extract.  Concentration of cashew leaves extract was varied for electrochemical measurement i.e. 0, 100, 200, 300, 400 and 500 ppm. Furthermore, immersion time variation (0, 30 and 60 min) was used prior to electrochemical measurement. The electrochemical measurement results indicate that cashew leaves extract work effectively as green corrosion inhibitor of API 5L X52 in acidic media. The performance of this green corrosion inhibitor was optimum at concentration of 500 ppm and 60 min of immersion time. Cashew leaves extract was mixed-type inhibitor because the corrosion potential value shifted less than 85 mV. The Increasing of surface resistance value and the decreasing in the capacitance of double layer due to the adsorption process of cashew leaves extract molecules on the API 5L X52 steel surface.

HIGHLIGHTS

  • Cashew (Anacardium Occidentale) leaves extract as green corrosion inhibitor is a novelty of this research
  • Cashew leaves extract delivers up to 96 % inhibition efficiency with 500 ppm of concentration and 60 min of immersion time
  • ElS has confirmed that cashew leaves extract inhibits the corrosion process of API 5L X52 in acidic media by boosting the impedance
  • Cashew leaves extract contains active corrosion inhibiting agents such as polyphenol, tannin, flavonoid and alkaloid
  • The adsorption mechanism of cashew leaves extract obeys the Langmuir isotherm


GRAPHICAL ABSTRACT

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

References

K Ranjbar and SRA Zaree. Longitudinal fracture and water accumulation at 6 o’clock position of an API 5L X52 oil pipeline. Eng. Fail. Anal. 2021; 129, 105691.

A Nikitasari, G Priyotomo, A Royani and S Sundjono. Exploration of eucheuma seaweed algae extract as a novel green corrosion inhibitor for API 5L carbon steel in hydrochlorid acid medium. Int. J. Eng. 2022; 35, 596-603.

AE Vázquez, R González-Olvera, DM Cerros, GE Negrón Silva, IA Figueroa, FJ Rodríguez Gómez, M Castro, A Miralrio and L Huerta. Inhibition of acid corrosion in API 5L X52 steel with 1,2,3-triazole derivatized from benzyl alcohol: Experimental and theoretical studies. J. Mol. Struct. 2021; 1242, 130731.

MA Bidi, M Azadi and M Rassouli. A new green inhibitor for lowering the corrosion rate of carbon steel in 1 M HCl solution: Hyalomma tick extract. Mater. Today Commun. 2020; 24, 100996.

A Mathina and R Rajalakshmi. Corrosion inhibition of mild steel in acid medium using Canna Indica as green corrosion inhibitor. Rasayan J. Chem. 2016; 9, 56-66.

E Berdimurodov, A Kholikov, K Akbarov, L Guo, S Kaya, DK Verma, M Rbaa and O Dagdag. Novel glycoluril pharmaceutically active compound as a green corrosion inhibitor for the oil and gas industry. J. Electroanal. Chem. 2022; 907, 116055.

N Subekti, JW Soedarsono, R Riastuti and FD Sianipar. Development of environmental friendly corrosion inhibitor from the extract of areca flower for mild steel in acidic media. East. Eur. J. Enterp. Technol. 2020; 2, 34-45.

RT Loto, T Olukeye and E Okorie. Synergistic combination effect of clove essential oil extract with basil and atlas cedar oil on the corrosion inhibition of low carbon steel. S. Afr. J. Chem. Eng. 2019; 30, 28-41.

P Parthipan, J Narenkumar, P Elumalai, PS Preethi, AUR Nanthini, A Agrawal and A Rajasekar. Neem extract as a green inhibitor for microbiologically influenced corrosion of carbon steel API 5LX in a hypersaline environments. J. Mol. Liq. 2017; 240, 121-7.

AA Olajire. Corrosion inhibition of offshore oil and gas production facilities using organic compound inhibitors: A review. J. Mol. Liq. 2017; 248, 775-808.

F Hashim, K Al-Azawi, SB Al-Bghdadi, LM Shaker and A Al-Amiery. Experimental and theoretical approach to the corrosion inhibition of mild steel in HCl solution by a newly coumarin. Proceedings 2019; 41, 15.

M Gopiraman, P Sakunthala, D Kesavan, V Alexramani, IS Kim and N Sulochana. An investigation of mild carbon steel corrosion inhibition in hydrochloric acid medium by environment friendly green inhibitors. J. Coatings Technol. Res. 2012; 9, 15-26.

A Singh, KR Ansari, DS Chauhan, MA Quraishi and S Kaya. Anti-corrosion investigation of pyrimidine derivatives as green and sustainable corrosion inhibitor for N80 steel in highly corrosive environment: Experimental and AFM/XPS study. Sustain. Chem. Pharm. 2020; 16, 100257.

NO Eddy, SA Odoemelam and IN Ama. Ethanol extract of Ocimum gratissimum as a green corrosion inhibitor for the corrosion of mild steel in H2SO4. Green Chem. Lett. Rev. 2010; 3, 165-72.

A Belakhdar, H Ferkous, S Djellali, R Sahraoui, H Lahbib, BY Amor, A Erto, M Balsamo and Y Benguerba. Computational and experimental studies on the efficiency of Rosmarinus officinalis polyphenols as green corrosion inhibitors for XC48 steel in acidic medium. Colloids Surf. 2020; 606, 125458.

M Goyal, H Vashisht, A Kumar, S Kumar, I Bahadur, F Benhiba and A Zarrouk. Isopentyltriphenylphosphonium bromideionic liquid as a newly effective corrosion inhibitor on metal-electrolyte interface in acidic medium: Experimental, surface morphological (SEM-EDX & AFM) and computational analysis. J. Mol. Liq. 2020; 316, 113838.

Y Liu, Z Song, W Wang, L Jiang, Y Zhang, M Guo, F Song and N Xu. Effect of ginger extract as green inhibitor on chloride-induced corrosion of carbon steel in simulated concrete pore solutions. J. Clean. Prod. 2019; 214, 298-307.

K Hanini, B Merzoug, S Boudiba, I Selatnia, H Laouer and S Akkal. Influence of different polyphenol extracts of Taxus baccata on the corrosion process and their effect as additives in electrodeposition. Sustain. Chem. Pharm. 2019; 14, 100189.

ME Azzouzi, K Azzaoui, I Warad, B Hammouti, S Shityakov, R Sabbahi, S Saoiabi, MH Youssoufi, N Akartasse, S Jodeh, A Lamhamdi and A Zarrouk. Moroccan, Mauritania, and senegalese gum Arabic variants as green corrosion inhibitors for mild steel in HCl: Weight loss, electrochemical, AFM and XPS studies. J. Mol. Liq. 2022; 347, 118354.

GS Jassim, AMB Al-Dhalimy, AS Noori, MH Shadhar, MM Kadhim, HA Almashhadani, AM Rheima and P Liu. Study the application of new type green corrosion inhibitors for iron metal. Inorg. Chem. Commun. 2020; 142, 109650.

T Kalyn, L Poberezhny, P Popovych, Y Rudiak, O Korol and L Poberezhna. Evaluation of the green inhibitor effect on the corrosion of pipeline steel in NS4 medium. Procedia Struct. Integr. 2022; 36, 313-7.

M Zhang, L Guo, M Zhu, K Wang, R Zhang, Z He, Y Lin, S Leng, VC Anadebe and X Zheng. Akebia trifoliate koiaz peels extract as environmentally benign corrosion inhibitor for mild steel in HCl solutions: Integrated experimental and theoretical investigations. J. Ind. Eng. Chem. 2021; 101, 227-36.

NA Odewunmi, SA Umoren and ZM Gasem. Watermelon waste products as green corrosion inhibitors for mild steel in HCl solution. J. Environ. Chem. Eng. 2015; 3, 286-96.

H Hassannejad and A Nouri. Sunflower seed hull extract as a novel green corrosion inhibitor for mild steel in HCl solution. J. Mol. Liq. 2018; 254, 377-82.

A Zakeri, E Bahmani and ASR Aghdam. Plant extracts as sustainable and green corrosion inhibitors for protection of ferrous metals in corrosive media: A mini review. Corros. Commun. 2022; 5, 25-38.

S Cherrad, A A Alrashdi, HS Lee, YE Aoufir, H Lgaz, B Satrani, M Ghanmi, EM Aouane and A Chaouch. Cupressus arizonica fruit essential oil: A novel green inhibitor for acid corrosion of carbon steel: Cupressus arizonica fruit essential oil. Arab. J. Chem. 2022; 15, 103849.

LRL Santos, DA Leal, CEB Marino and IC Riegel-Vidotti. pH-triggered release of tannic acid as green corrosion inhibitor for carbon steel. Mater. Today Commun. 2022; 31, 103730.

MH Fekri, F Omidali, MM Alemnezhad and A Ghaffarinejad. Turnip peel extract as green corrosion bio-inhibitor for copper in 3.5 % NaCl solution. Mater. Chem. Phys. 2022; 286, 126150.

APS Kaban, A Ridhova, G Priyotomo, B Elya, A Maksum, Y Sadeli, S Sutopo, T Aditiyawarman, R Riastuti and JW Soedarsono. Development of white tea extract as green corrosion inhibitor in mild steel under 1 M hydrochloric acid solution. East. Eur. J. Enterp. Technol. 2021; 2, 6-20.

M Mehdipour, B Ramezanzadeh and SY Arman. Electrochemical noise investigation of Aloe plant extract as green inhibitor on the corrosion of stainless steel in 1M H2SO4. J. Ind. Eng. Chem. 2015; 21, 318-27.

S Wan, H Wei, R Quan, Z Luo, H Wang, B Liao and X Guo. Soybean extract firstly used as a green corrosion inhibitor with high efficacy and yield for carbon steel in acidic medium. Ind. Crops Prod. 2022; 187, 115354.

H Mohammed and SB Sobri. Corrosion inhibition studies of cashew nut (Anacardium occidentale) on carbon steel in 1.0 M hydrochloric acid environment. Mater. Lett. 2018; 29, 82-4.

O Olawale, JO Bello and P Akinbami. A study on corrosion inhibitor of mild-steel in hydrochloric acid using cashew waste. Int. J. Mod. Eng. Res. 2015; 5, 25-30.

U Layek, K Bera, B Bera, S Bisui, SK Pattanayek and P Karmakar. Assessment of yield enhancement in cashew (Anacardium occidentale L.) by the pollinator sharing effect of magnetic bee-friendly plants in India. Acta Ecol. Sin. 2021; 41, 243-52.

AA Dahlia and H Hasnawati. Isolasi dan identifikasi golongan kimia aktif antioksidan ekstrak etanol daun jambu mete (Anacardium occidentale L.) (in Indonesian). J. Fitofarmaka Indones. 2016; 1, 24-30.

MJ Kassim and TK Wei. Plants polyphenols: An alternative source for green corrosion inhibitor. In: Proceedings of the 2nd Annual International Conference Syiah Kuala University, Banda Aceh, Indonesia. 2012, p. 22-4.

S Chihi, N Gherraf, B Alabed and S Hameurlain. Inhibition effect of flavonoid extract of Euphorbia guyoniana on the corrosion of mild steel in H2SO4 medium. J. Fundam. Appl. Sci. 2015; 1, 31-9.

A Pambudi, SN Noriko, R Azhari and PR Azura. Identifikasi bioaktif golongan flavonoid tanaman anting-anting (Acalypha indica L.) (in Indonesian). J. Al-Azhar Indones. Seri Sains Teknol. 2015; 2, 178-87.

Y Boughoues, M Benamira, L Messaadia and N Ribouh. Adsorption and corrosion inhibition performance of some environmental friendly organic inhibitors for mild steel in HCl solution via experimental and theoretical study. Colloids Surf. A: Physicochem. Eng. Asp. 2020; 593, 124610.

A Nikitasari, Sundjono, G Priyotomo and A Royani. Sargassum seaweed extract as a novel green corrosion inhibitor for API-5L carbon steel. Int. J. Corros. Scale Inhib. 2021; 10, 1689-99.

A Nikitasari, E Mabruri and R Riastuti. Corrosion behavior of CA6NM in simulated geothermal brine highlighted by Electrochemical Impedance Spectroscopy (EIS). Eng. Appl. Sci. Res. 2021; 48, 359-67.

M Radi, R Melian, M Galai, N Dkhirche, M Makha, C Verma, C Fernandez and M EbnTouhami. Pumpkin seeds as an eco-friendly corrosion inhibitor for 7075-T6 alloy in 3.5 % NaCl solution: Electrochemical, surface and computational studies. J. Mol. Liq. 2021; 337, 116547.

L Quej-Aké, R Cabrera-Sierra, E Arce-Estrada and J Marín-Cruz. EIS evaluation of the effect of neutralizing and inhibitor compounds on corrosion process of 1018 carbon steel in acid solutions typical of atmospheric distillation plants. Int. J. Electrochem. Sci. 2008; 3, 56-66.

FSD Souza, C Giacomelli, RS Gonçalves and A Spinelli. Adsorption behavior of caffeine as a green corrosion inhibitor for copper. Mater. Sci. Eng. C 2012; 32, 2436-44.

Downloads

Published

2023-03-17

How to Cite

Nikitasari, A. ., Astuti, I. M. ., Musabikha, S. ., Kusumastuti, R. ., Prifiharni, S. ., & Priyotomo, G. . (2023). Chasew (Anacardium Occidentale) Leaves Extract as Green Corrosion Inhibitor of API 5L X52 in Acidic Media. Trends in Sciences, 20(7), 4733. https://doi.org/10.48048/tis.2023.4733