Effects on Structural Morphological and Optical Properties Pure and CuO/ZnO Nanocomposite

Authors

DOI:

https://doi.org/10.48048/tis.2022.3092

Keywords:

XRD, FESEM-EDX, FTIR, UV-Vis, CuO, ZnO, CuO/ZnO Composites

Abstract

In the present work, synthesis of CuO, ZnO and CuO/ZnO Nonocomposites and their properties have been investigated. CuO, ZnO and CuO/ZnO NC were synthesized using the co-precipitation method. The nanocomposite materials were structural, morphological and optical properties characterized by X-ray diffraction (XRD), Field Emission Scanning Electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDX), Fourier transform infrared spectroscopy (FTIR), UV-Vis Spectroscopy. The results of the XRD analysis exhibited that the pure CuO, ZnO and CuO/ZnO NC has a nanometer size with an average of 15.19 nm. The UV-vis analysis showed that the CuO, ZnO and CuO/ZnO NC has a band-gap of 3.31 and 2.35 eV. FTIR investigation revealed that the vibration of ZnO was observed at 561 cm-1 whereas CuO was at 602 cm-1 and composites 612 cm-1. The FESEM-EDX analysis revealed that the ZnO has a hexagonal structure whereas the CuO has a monoclinic structure.

HIGHLIGHTS

  • Present investigation deals with CuO, ZnO, and CuO/ZnO composites nanoparticles harvested as Co-Precipitation Method
  • Various characterisation techniques were used to investigate the structural, optical, and morphological features of produced nanoparticles composites
  • Investigation the effects of different properties of the CuO, ZnO and CuO/ZnO composites nanoparticles as well as Co-Precipitation method


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References

JH Huang, JX Chen, YF Tu, Y Tian, D Zhou, G Zheng, JP Sang and QM Fu. Preparation and photocatalytic activity of CuO/ZnO composite nanostructured films. Mater. Res. Express 2018; 6, 015035.

MG Lines. Nanomaterials for practical functional uses J. Alloys Comp. 2008; 449, 242-5.

H Amrulloh, YS Kurniawan, C Ichsan, J Jelita, W Simanjuntak, RTM Situmeang and PA Krisbiantoro. Highly efficient removal of Pb (II) and Cd (II) ions using magnesium hydroxide nanostructure prepared from seawater bittern by electrochemical method. Colloid. Surf. Physicochem. Eng. Aspect 2021; 631, 127687.

S Sharma, K Kumar, N Thakur, S Chauhan and M Chauhan. The effect of shape and size of ZnO nanoparticles on their antimicrobial and photocatalytic activities: A green approach. Bull. Mater. Sci. 2020; 43, 20.

H Amrulloh, A Fatiqin, W Simanjuntak, H Afriyani and A Annissa. Antioxidant and antibacterial activities of magnesium oxide nanoparticles prepared using aqueous extract of Moringa oleifera bark as green agents. J. Multidiscip. Appl. Nat. Sci. 2021; 1, 44-53.

YF He, DY Chu and Z Zhuo. Cycle stability of dual-phase lithium titanate (LTO)/TiO2 nanowires as lithium battery anode. J. Multidiscip. Appl. Nat. Sci. 2021; 1, 54-61.

A Fadaka, O Aluko, S Awawu and K Theledi. Green synthesis of gold nanoparticles using Pimenta dioica leaves aqueous extract and their application as photocatalyst, antioxidant, and antibacterial agents. J. Multidiscip. Appl. Nat. Sci. 2021; 1, 78-88.

A Fatiqin, H Amrulloh, W Simanjuntak, I Apriani, RAHT Amelia, Syarifah, RN Sunarti and ARP Raharjeng. Characteristics of nano-size MgO prepared using aqueous extract of different parts of Moringa oleifera plant as green synthesis agents. AIP Conf. Proc. 2021; 2331, 040001.

H Amrulloh, A Fatiqin, W Simanjuntak, H Afriyani and A Annissa. Bioactivities of nano-scale magnesium oxide prepared using aqueous extract of Moringa Oleifera leaves as green agent. Adv. Nat. Sci. Nanosci. Nanotechnol. 2021; 12, 015006.

A Fatiqin, H Amrulloh and W Simanjuntak. Green synthesis of MgO nanoparticles using Moringa oleifera leaf aqueous extract for antibacterial activity. Bull. Chem. Soc. Ethiopia 2021; 35, 161-70.

H Amrulloh, W Simanjuntak, RTM Situmeang, SL Sagala, R Bramawanto, A Fatiqin, R Nahrowi and M Zuniati. Preparation of nano-magnesium oxide from Indonesia local seawater bittern using the electrochemical method. Inorg. Nano-Metal Chem. 2020; 50, 693-8.

HB Na, XF Zhang, M Zhang, ZP Deng, XL Cheng, LH Huo and S Gao. A fast response/recovery ppb-level H2S gas sensor based on porous CuO/ZnO heterostructural tubule via confined effect of absorbent cotton. Sensor. Actuator. B Chem. 2019; 29, 126816.

J Singh, T Dutta, KH Kim, M Rawat, P Samddar and P Kumar. ‘Green’ synthesis of metals and their oxide nanoparticles: Applications for environmental remediation. J. Nanobiotechnol. 2018; 16, 84.

J Lillo-Ramiro, JM Guerrero-Villalba, MDL Mota-Gonz´alez, FS Aguirre-Tostado, G Guti´errez-Heredia, I Mejía-Silva and A Carrillo-Castillo. Optical and microstructural characteristics of CuO thin films by sol gel process and introducing in non-enzymatic glucose biosensor applications. Optik 2021; 229, 166238.

R Nayak, FA Ali, DK Mishra, D Rayd, VK Aswald, SK Sahooe and B Nandaa. Fabrication of CuO nanoparticle: An efficient catalyst utilized for sensing and degradation of phenol. J. Mater. Res. Tech. 2020; 9, 11045-59.

ME Grigore, ER Biscu, AM Holban, MC Gestal and AM Grumezescu. Methods of synthesis, properties and biomedical applications of CuO nanoparticles. Pharmaceuticals 2016; 9, 75.

R Saemi, E Taghavi, H Jafarizadeh-Malmiri and N Anarjan. Fabrication of green ZnO nanoparticles using walnut leaf extract to develop an antibacterial film based on polyethylene-starch-ZnO NPs. Green Process. Synth. 2021; 10, 112-4.

S Alamdari, MS Ghamsari, C Lee, W Han, HH Park, MJ Tafreshi, H Afarideh and MHM Ara. Preparation and characterization of zinc oxide nanoparticles using leaf extract of Sambucus ebulus. Appl. Sci. 2020; 10, 3620.

AAM Sakib, SM Masum, J Hoinkis, R Islam and MAI Molla. Synthesis of CuO/ZnO nanocomposites and their application in photodegradation of toxic textile dye. J. Compos. Sci. 2019; 3, 91.

A Marcu and C Viespe. Laser-grown ZnO nanowires for room-temperature SAW-sensor applications. Sensor. Actuator. B 2015; 208, 1-6.

GA Govindasamy, RBSMN Mydin, S Sreekantan and NH Harun. Compositions and antimicrobial properties of binary ZnO-CuO nanocomposites encapsulated calcium and carbon from Calotropis gigantea targeted for skin pathogens. Sci. Rep. 2021; 11, 99.

A Anu and MA Khadar. CuO-ZnO nanocomposite films with efficient interfacial charge transfer characteristics for optoelectronic applications. SN Appl. Sci. 2019; 1, 1057.

SA Hassanzadeh-Tabrizi, MM Motlagh and S Salahshour. Synthesis of ZnO/CuO nanocomposite immobilized on γ-Al2O3 and application for removal of methyl orange. Appl. Surf. Sci. 2016; 384, 237-43.

N Abraham, RR Krishnakumar, C Unni and D Philip. Simulation studies on the responses of ZnO-CuO/CNT nanocomposite based SAW sensor to various volatile organic chemicals. J. Sci. Adv. Mater. Dev. 2019; 4, 125-31.

S Das and VC Srivastava. Synthesis and characterization of ZnO/CuO nanocomposite by electrochemical method. Mater. Sci. Semicond. Process. 2017; 57, 173-7.

SM Mali, SS Narwade, YH Navale, SB Tayade, RV Digraskar, VB Patil, AS Kumbhar and BR Sathe. Heterostructural CuO-ZnO nanocomposites: A highly selective chemical and electrochemical NO2 sensor. ACS Omega 2019; 4, 20129-41.

NLU Vo, TTV Nguyen, T Nguyen, PA Nguyen, VM Nguyen, NH Nguyen, VL Tran, NA Phan and KPH Huynh. Antibacterial shoe insole-coated CuO-ZnO nanocomposite synthesized by the sol-gel technique. J. Nanomater. 2020; 2020, 8825567.

J Sandhya and S Kalaiselvam. UV responsive quercetin derived and functionalized CuO/ZnO nanocomposite in ameliorating photocatalytic degradation of rhodamine B dye and enhanced biocidal activity against selected pathogenic strains. J. Environ. Sci. Health A 2021; 56, 835-48.

CP Sagita, L Nulandaya and YS Kurniawan. Efficient and low-cost removal of methylene blue using activated natural kaolinite material. J. Multidiscip. Appl. Nat. Sci. 2021; 1, 69-79.

TT Li, N Bao, A Geng, H Yu, Y Yang and XT Dong. Study on room temperature gas-sensing performance of CuO film-decorated ordered porous ZnO composite by In2O3 sensitization. R. Soc. Open Sci. 2018; 5, 171788.

S Soltani, U Rashid, IA Nehdi and SI Al-Resayes. Esterification of palm fatty acid distillate using a sulfonated mesoporous CuO‐ZnO mixed metal oxide catalyst. Chem. Eng. Tech. 2017; 40, 1931-9.

MA Khan, Y Wahab, R Muhammad, M Tahir and S Sakrani. Catalyst-free fabrication of novel ZnO/CuO core-Shell nanowires heterojunction: Controlled growth, structural and optoelectronic properties. Appl. Surf. Sci. 2018; 435, 718-32.

D Manyasree, KM Peddi and R Ravikumar. CuO nanoparticles: Synthesis, characterization and their bactericidal efficacy. Int. J. Appl. Pharmaceut. 2017; 9, 71-4.

R Kumar, O Al-Dossary, G Kumar and A Umar. Zinc oxide nanostructures for NO2 gas-sensor applications: A review. Nano-Micro Lett. 2015; 7, 97-120.

S Das and VC Srivastava. An overview of the synthesis of CuO-ZnO nanocomposite for environmental and other applications. Nanotechnol. Rev. 2018; 7, 267-82.

B Fatima, SI Siddiqui, R Ahmad, NTT Linh and VN Thai. CuO-ZnO-CdWO4: A sustainable and environmentally benign photocatalytic system for water cleansing. Environ. Sci. Pollut. Res. 2021; 28, 53793-803.

W Fang, L Yu and L Xu. Preparation, characterization and photocatalytic performance of heterostructured CuO-ZnO-loaded composite nanofiber membranes. Beilstein J. Nanotechnol. 2020; 11, 631-50.

D Saravanakkumar, HA Oualid, Y Brahmi, A Ayeshamariam, M Karunanaithy, AM Saleem, K Kaviyarasu, S Sivaranjani and M Jayachandran. Synthesis and characterization of CuO/ZnO/CNTs thin films on copper substrate and its photocatalytic applications. OpenNano 2019; 4, 100025.

G Zhou, L Long, P Wang, Y Hu, Q Zhang, C Liu. Designing CuO/ZnO nanoforest device toward optimal photocatalytic performance through structure and facet engineering. Mater. Lett. 2020; 273, 127907.

A Sankaran and K Kumaraguru. The novel two step synthesis of CuO/ZnO and CuO/CdO nanocatalysts for enhancement of catalytic activity. J. Mol. Struct. 2020; 1221, 128772.

MS AlSalhi, A Sakthisabarimoorthi, S Devanesan, SAMB Dhas and M Jose. Study on photocatalytic and impedance spectroscopy investigations of composite CuO/ZnO nanoparticles. J. Mater. Sci. Mater. Electron. 2019; 30, 13708-18.

H Salari and M Sadeghinia. MOF-templated synthesis of nano Ag2O/ZnO/CuO heterostructure for photocatalysis. J. Photochem. Photobiol. A Chem. 2019; 376, 279-87.

P Sathishkumar, R Sweena, JJ Wu and S Anandan. Synthesis of CuO-ZnO nanophotocatalyst for visible light assisted degradation of a textile dye in aqueous solution. Chem. Eng. J. 2011; 171, 136-40.

M Naseer, U Aslam, B Khalid and B Chen. Green route to synthesize zinc oxide nanoparticles using leaf extracts of Cassia fistula and Melia azadarach and their antibacterial potential. Sci. Rep. 2020; 10, 9055.

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Published

2022-11-19

How to Cite

Sable, P., Thabet, N. ., Yaseen, J. ., & Dharne, G. . (2022). Effects on Structural Morphological and Optical Properties Pure and CuO/ZnO Nanocomposite. Trends in Sciences, 19(24), 3092. https://doi.org/10.48048/tis.2022.3092